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近年来养殖废水中四环素(TC)污染日趋严重,为了缓解这一现状,以阳离子表面活性剂双十二烷基二甲基溴化铵(DDAB)对凹凸棒土(ATP)进行改性,制得能高效吸附TC的材料,并对其吸附性能进行研究。实验结果表明:DDAB/ATP对TC的饱和吸附容量达437.32 mg·g-1。当模拟DDAB/ATP对地表水进行吸附时,TC去除率均在99.6%以上,满足污染水体中TC的去除要求。再生研究表明,经4次循环后,去除率仍在90%以上,表明DDAB/ATP具有良好的再生性能。
Abstract:Recently, tetracycline(TC) pollution in aquaculture wastewater is getting more and more serious.In order to alleviate this situation, attapulgite(ATP) was modified with the cationic surfactant didodecyl dimethyl ammonium bromide(DDAB) to prepare a material with high adsorption capacity for TC,and its adsorption properties were studied.The results shows that the saturated adsorption capacity of DDAB/ATP for TC reaches 437.32 mg·g-1.When DDAB/ATP is applied to the adsorption of surface water in simulation, the TC removal rate is above 99.6%,which far meets the removal requirements of TC in the actual polluted water.The regeneration experiment shows that after four cycles, the removal rate still reaches more than 90%,indicating that DDAB/ATP has good regeneration performance.
[1] DINESHBABU N,JAYAPRAKASH R N,KARUPPASAMY P,et al.Investigation on tetracycline degradation and bactericidal properties of binary and ternary ZnO/NiO/g-C3N4 composites prepared by a facile co-precipitation method[J].Journal of Environmental Chemical Engineering,2022,10(3):107368.
[2] ZHAO W G,TIAN Y M,CHU X X,et al.Preparation and characteristics of a magnetic carbon nanotube adsorbent:its efficient adsorption and recoverable performances[J].Separation and Purification Technology,2021,257:117917.
[3] KHAZAIE A,KIA H,MONIRI E,et al.Adsorption modeling of tetracycline removal by multi-walled carbon nanotub-e functionalized with aspartic acid and poly-pyrrole using bayesian optimized artificial neural network[J].Journal of the Taiwan Institute of Chemical Engineers,2023,144:104743.
[4] ZHUO S N,DAI T C,REN H Y,et al.Simultaneous adsorption of phosphate and tetracycline by calcium modified corn stover biochar:performance and mechanism[J].Bioresource Technology,2022,359:127477.
[5] WU T,LIANG Q H,TANG L,et al.Construction of a novel S-scheme heterojunction piezoelectric photocatalyst V-BiOIO3/FTCN and immobilization with floatability for tetracycline degradation[J].Journal of Hazardous Materials,2023,443(Part B):130251.
[6] YE J,LI C X,YAN Y S.Core-shell ZIF-67/ZIF-8-derived sea urchin-like cobalt/nitrogen co-doped carbon nanotube hollow frameworks for ultrahigh adsorption and catalytic activities[J].Journal of the Taiwan Institute of Chemical Engineers,2020,112:202-211.
[7] WANG J H,LEI S L,LIANG L Q.Preparation of porous activated carbon from semi-coke by high temperature activation with KOH for the high-efficiency adsorption of aqueous tetracycline[J].Applied Surface Science,2020,530:147187.
[8] XIA J,GAO Y X,YU G.Tetracycline removal from aqueous solution using zirconium-based metal-organic frameworks (Zr-MOFS) with different pore size and topology:adsorption isotherm,kinetic and mechanism studies[J].Journal of Colloid and Interface Science,2021,590:495-505.
[9] ORTIE-RAMOS U,LEYVA-RAMOS R,MENDOEA-MENDOZA E,et al.Removal of tetracycline from aqueous solutions by adsorption on raw Ca-bentonite.effect of operating conditions and adsorption mechanism[J].Chemical Engineering Journal,2022,432:134428-134441.
[10] 董良飞,郜飞,刘会东,等.凹凸棒土/玉米秸秆生物炭制备及对四环素的吸附[J].常州大学学报(自然科学版),2023,35(2):46-58.
[11] UNDABEYTIA T,NIR S,SáNCHEZ-VERDEJO T,et al.A clay-vesicle system for water purification from organic pollutants[J].Water Research,2008,42(4-5):1211-1219.
[12] HUANG J H,WANG X G,JIN Q Z,et al.Removal of phenol from aqueous solution by adsorption onto OTMAC-modified attapulgite[J].Journal of Environmental Management,2007,84(2):229-236.
[13] HUANG J H,LIU Y F,JIN Q Z,et al.Adsorption studies of a water soluble dye,Reactive Red MF-3B,using sonication-surfactant-modified attapulgite clay[J].Journal of Hazardous Materials,2007,143(1-2):541-548.
[14] 柴琴琴.凹凸棒粘土的有机改性及其在养殖废水中的应用[D].杨凌:西北农林科技大学,2016.
[15] 秦小宁.改性凹凸棒土和膨润土对水中四环素类抗生素的吸附去除研究[D].兰州:兰州交通大学,2020.
[16] QV X Y,JIANG J G.Toxicity evaluation of two typical surfactants to Dunaliella bardawil,an environmentally tolerant Alga[J].Environmental Toxicology and Chemistry,2013,32(2):426-433.
[17] RAKHYM A B,SEILKHANOVA G A,MASTAI Y.Physicochemical evaluation of the effect of natural zeolite modification with didodecyldimethylammonium bromide on the adsorption of Bisphenol-A and Propranolol Hydrochloride[J].Microporous and Mesoporous Materials,2021,318:111020.
[18] SAITOH T,SHIBAYAMA T.Removal and degradation of β-lactam antibiotics in water using didodecyldimethylammonium bromide-modified montmorillonite organoclay[J].Journal of Hazardous Materials,2016,317:677-685.
[19] GAROMA T K J.Investigation of surfactant-modified activated carbon for recycled water disinfection[J].Water Science and Technology,2010,62(8):1755-1766.
[20] HEDAYATI M S,LI L Y.Removal of polycyclic aromatic hydrocarbons from aqueous media using modified clinoptilolite[J].Journal of Environmental Management,2020,273(1):111113.
[21] 孙雪梅,吉喆,高娅玲,等.线性扫描极谱法检测环境水样中四环素[J].分析科学学报,2016,32(6):753-757.
[22] CHEN L F,WU X R,LIU C,et al.Study on removal of Microcystis aeruginosa and Cr (VI) using attapulgite-Fe3O4 magnetic composite material(MCM)[J].Algal Research,2021,60:102501.
[23] 王荣.改性ATP吸附剂的制备及其对废水中新兴污染物的去除研究[D].临汾:山西师范大学,2021.
[24] MUNIR M,NAIAR M F,ZAFAR MN,et al.Effective adsorptive removal of methylene blue from water by didodecyldimethylammonium bromide-modified brown clay[J].ACS Omega,2020,5(27):16711-16721.
[25] 徐永刚,宇万太,马强,等.环境中抗生素及其生态毒性效应研究进展[J].生态毒理学报,2015,10(3):11-27.
[26] DA SILVA BRUCKMANN F,SCANORR C E,DA ROSA SALLFS T,et al.Highly efficient adsorption of tetracycline using chitosan-based magnetic adsorbent[J].Polymers,2022,14(22):4854-4854.
[27] 阳春,陈晓虹,王瀚,等.双金属掺杂UiO-66及其对四环素的吸附特性[J].中国给水排水,2023,39(21):78-85.
[28] 王琪慧,刘松,文茜,等.牛磺酸改性埃洛石纳米管的制备及其对四环素的吸附性能[J].合成化学,2023,31(9):673-680.
[29] 张文博,贺丹丹,王九玲,等.壳聚糖/磁性铁凹凸棒石对四环素的吸附研究[J].工业水处理,2023,43(7):128-134.
[30] GUO S X,GAO M L,SHEN T,et al.Effective adsorption of sulfamethoxazole by novel Organo-Vts and their mechanistic insights[J].Microporous and Mesoporous Materials,2019,286:36-44.
基本信息:
DOI:10.16246/j.issn.1673-5072.2025.06.008
中图分类号:TQ424;X713;X52
引用信息:
[1]李鑫,周嫄,赵平,等.DDAB改性凹凸棒土对水体中四环素的吸附[J].西华师范大学学报(自然科学版),2025,46(06):614-622.DOI:10.16246/j.issn.1673-5072.2025.06.008.
基金信息:
国家自然科学基金项目(42267009)
2025-01-16
2025-01-16
2025-01-16